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Synthesis of 2-(selenophen-2-yl) pyrroles and their electropolymerization to electrochromic nanofilms

journal contribution
posted on 2009-06-22, 00:00 authored by B Trofimov, E Schmidt, A Mikhaleva, Cristina Pozo-GonzaloCristina Pozo-Gonzalo, J Pomposo, M Salsamendi, N Protzuk, N Zorina, A Afonin, A Vashchenko, E Levanova, G Levkovskaya
The divergent syntheses of 2-(selenophen-2-yl)pyrroles and their N-vinyl derivatives from available 2-acylselenophenes and acetylenes in a one-pot procedure make these exotic heterocyclic ensembles accessible. Now we face a potentially vast area for exploration with a great diversity of far-reaching consequences including conducting electrochromic polymers with repeating of pyrrole and selenophene units (emerging rivalry for polypyrroles and polyselenophenes), the synthesis of functionalized pyrrole–selenophene assembles for advanced materials, biochemistry and medicine, exciting models for theory of polymer conductivity.

History

Journal

Chemistry - a European journal

Volume

15

Issue

26

Pagination

6435 - 6445

Publisher

Wiley - V C H Verlag GmbH & Co. KGaA

Location

Weinheim, Germany

ISSN

0947-6539

eISSN

1521-3765

Language

eng

Publication classification

C1.1 Refereed article in a scholarly journal

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