File(s) under permanent embargo
The effect of metal ligands on the adsorption of metal coordination complexes on polystyrene nano-beads
journal contribution
posted on 2019-09-20, 00:00 authored by C Dionigi, Alessandra SuttiAlessandra Sutti, Surya SubiantoSurya Subianto, A Venturini, L Ortolani, F Corticelli, G RuaniNanostructured metal oxides showing geometrically controlled shape are often shaped by the calcination of selected metal coordination complexes adsorbed on sacrificial polystyrene beads (PSB) in aqueous suspensions. The design of an alternative, more sustainable, method to guide the adsorption of titanium oxide precursors on sacrificial carriers into specific morphologies has been explored as part of a global strategy to produce new nano-engineered metal oxides. Among various titanium coordination complexes, ligands like β-diketones or β-ketoesters have been often investigated due to their chelating and stabilizing effect on the titanium. In particular, titanium coordination complexes like Titanium(IV)bis(ammonium lactato) dihydroxide and titanium diisopropoxide bis(acetylacetonate) have been largely applied in the fabrication of nanostructured titanium oxide films in last-generation photovoltaic devices. To date the driving force for the spontaneous adsorption of precursors on non-modified PSB had not been investigated. We propose that a major driver is the interaction between the polystyrene surface of PSB and the molecular structure of the organic ligands of the metal-complexes. The proposed mechanism is supported by proton nuclear magnetic resonance spectroscopy of the starting colloidal suspensions and by electron microscopy of the resulting nanostructured metal oxides.
History
Journal
Colloids and surfaces A: physicochemical and engineering aspectsVolume
577Pagination
541 - 547Publisher
ElsevierLocation
Amsterdam, The NetherlandsPublisher DOI
ISSN
0927-7757eISSN
1873-4359Language
engPublication classification
C1 Refereed article in a scholarly journalUsage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC