Deakin University
Browse

Towards a high-flux separation layer from hexagonal lyotropic liquid crystals for thin-film composite membranes

Download (4 MB)
Version 3 2024-06-19, 06:32
Version 2 2024-06-05, 23:52
Version 1 2021-11-15, 15:44
journal contribution
posted on 2021-01-01, 00:00 authored by Senlin GuSenlin Gu, B Yuan, B Bai, X Tong, L A O’dell, D Wang, Lingxue KongLingxue Kong, G Wang
Hexagonal lyotropic liquid crystals (HLLC) with uniform pore size in the range of 1~5 nm are highly sought after as promising active separation layers of thin-film composite (TFC) membranes, which have been confirmed to be efficient for water purification. The potential interaction between an amphiphile-based HLLC layer and the substrate surface, however, has not been fully explored. In this research, hydrophilic and hydrophobic microporous polyvinylidene fluoride (PVDF) substrates were chosen, respectively, to prepare TFC membranes with the active layers templated from HLLC, consisting of dodecyl trimethylammonium bromide, water, and a mixture of poly (ethylene glycol) diacrylate and 2-hydroxyethyl methacrylate. The pore size of the active layer was found to decrease by about 1.6 Å compared to that of the free-standing HLLC after polymerization, but no significant difference was observable by using either hydrophilic or hydrophobic substrates (26.9 Å vs. 27.1 Å). The water flux of the TFC membrane with the hydrophobic substrate, however, was higher than that with the hydrophilic one. A further investigation confirmed that the increase in water flux originated from a much higher porosity was due to the synergistic effect of the hydrophilic HLLC nanoporous material and the hydrophobic substrate.

History

Journal

Membranes

Volume

11

Issue

11

Article number

ARTN 842

Pagination

1 - 11

Publisher

MDPI / MDPI AG (Multidisciplinary Digital Publishing Institute)

Location

Basel, Switzerland

ISSN

2077-0375

eISSN

2077-0375

Language

English

Publication classification

C1.1 Refereed article in a scholarly journal