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UV-Cross-Linked Ionogels for all-solid-state rechargeable sodium batteries
journal contribution
posted on 2019-09-23, 00:00 authored by A F De Anastro, L Porcarelli, Matthias Hilder, C Berlanga, M Galceran, Patrick HowlettPatrick Howlett, Maria ForsythMaria Forsyth, D Mecerreyes© 2019 American Chemical Society. A simple method to prepare a mechanically robust ionogel film by fast (<1 min) UV photopolymerization of poly(ethylene glycol) diacrylate in the presence of an ionic liquid electrolyte based on N-propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide and sodium bis(fluorosulfonyl)imide is demonstrated. The ionogels showed very high ionic conductivity at 50 °C (6.5 × 10-3 S·cm-1) close to the liquid counterpart (7.8 × 10-3 S·cm-1). High salt concentration in the ionogels was beneficial for the sodium plating and stripping. Na/ionogel/NaFePO4 full cells delivered a high specific capacity of 152 mAh g-1 at 50 °C with good capacity retention.
History
Journal
ACS Applied Energy MaterialsVolume
2Issue
10Pagination
6960 - 6966Publisher
ACS PublicationsLocation
Washington, D.C.Publisher DOI
eISSN
2574-0962Language
engPublication classification
C1 Refereed article in a scholarly journalUsage metrics
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No categories selectedKeywords
polymer electrolyteionogelsodium batteryphotopolymerizationionic conductivitysolid-state batteryScience & TechnologyPhysical SciencesTechnologyChemistry, PhysicalEnergy & FuelsMaterials Science, MultidisciplinaryChemistryMaterials ScienceIONIC LIQUID ELECTROLYTESPOLYMER ELECTROLYTESPHYSICOCHEMICAL BEHAVIORTRANSFERENCE NUMBERLITHIUMCHALLENGESSAFE
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