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‘Cathodic’ electrochemiluminescence of [Ru(bpy)3]2+ and tri-n-propylamine confirmed as emission at the counter electrode
journal contribution
posted on 2019-06-21, 00:00 authored by A G Theakstone, Egan DoevenEgan Doeven, Xavier ConlanXavier Conlan, L Dennany, Paul FrancisPaul FrancisA new approach to examine electrochemiluminescence (ECL), in which the potentials at both the working and counter electrodes are measured and the emitted light is detected by a photomultiplier tube, camera and then a charge-coupled device (CCD) spectrometer, provides unequivocal evidence that the purported cathodic ECL of [Ru(bpy)3]2+ and tri-n-propylamine actually arises from anodic reactions at the counter electrode.
History
Journal
Chemical communicationsVolume
55Issue
49Pagination
7081 - 7084Publisher
Royal Society of ChemistryLocation
Cambridge, Eng.Publisher DOI
ISSN
1359-7345eISSN
1364-548XLanguage
engPublication classification
C1 Refereed article in a scholarly journalCopyright notice
2019, The Royal Society of ChemistryUsage metrics
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