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‘Cathodic’ electrochemiluminescence of [Ru(bpy)3]2+ and tri-n-propylamine confirmed as emission at the counter electrode

Version 2 2024-06-04, 04:58
Version 1 2019-06-27, 15:27
journal contribution
posted on 2024-06-04, 04:58 authored by AG Theakstone, Egan DoevenEgan Doeven, Xavier ConlanXavier Conlan, L Dennany, Paul FrancisPaul Francis
A new approach to examine electrochemiluminescence (ECL), in which the potentials at both the working and counter electrodes are measured and the emitted light is detected by a photomultiplier tube, camera and then a charge-coupled device (CCD) spectrometer, provides unequivocal evidence that the purported cathodic ECL of [Ru(bpy)3]2+ and tri-n-propylamine actually arises from anodic reactions at the counter electrode.

History

Journal

Chemical communications

Volume

55

Pagination

7081-7084

Location

Cambridge, Eng.

ISSN

1359-7345

eISSN

1364-548X

Language

eng

Publication classification

C1 Refereed article in a scholarly journal

Copyright notice

2019, The Royal Society of Chemistry

Issue

49

Publisher

Royal Society of Chemistry

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