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[P,P-Di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidato-k2N,N′]bis(pyridine-kN)lithium(I)
journal contribution
posted on 2002-04-01, 00:00 authored by Madeleine SchultzMadeleine Schultz, B F Straub, P HofmannThe crystal structure of lithium metal-organic compounds was studied. In the given compound, the bulky chelating monoanionic phosphine imidate ligand and two pyridine ligands bind to Li in a pseudo-tetrahedral arrangement with twofold symmetry. The results showed that the distance from Li to the N atoms of the aminophosphine imidate was 2.048 (5) Å while to the N atoms of the pyridine ligands, the distance was 2.114 (5) Å.