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[P,P-Di-tert-butyl-N-trimethylsilyl-P-(trimethylsilylamino)phosphine imidato-k2N,N′]bis(pyridine-kN)lithium(I)

Version 2 2024-06-05, 00:22
Version 1 2018-09-11, 15:36
journal contribution
posted on 2024-06-05, 00:22 authored by Madeleine SchultzMadeleine Schultz, BF Straub, P Hofmann
The crystal structure of lithium metal-organic compounds was studied. In the given compound, the bulky chelating monoanionic phosphine imidate ligand and two pyridine ligands bind to Li in a pseudo-tetrahedral arrangement with twofold symmetry. The results showed that the distance from Li to the N atoms of the aminophosphine imidate was 2.048 (5) Å while to the N atoms of the pyridine ligands, the distance was 2.114 (5) Å.

History

Journal

Acta Crystallographica Section C: Crystal Structure Communications

Volume

58

Pagination

256-257

Location

Copenhagen, Denmark

ISSN

0108-2701

Language

eng

Publication classification

C Journal article, C1.1 Refereed article in a scholarly journal

Issue

4

Publisher

Munksgaard