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14N Overtone Magic Angle Spinning NMR
Overtone NMR spectroscopy has the potential to provide high-resolution 14N solid-state NMR spectra. The technique was first developed during the 1980s but has only recently been successfully combined with magic angle spinning (MAS), providing improved sensitivity and resolution as well as enabling more advanced approaches such as indirect detection and signal enhancement methods. This report provides a brief background to 14N overtone NMR, describing the ways in which it differs from conventional NMR and the challenges that arise as a result. The effects of MAS on the overtone spectrum are then presented and illustrated with numerous experimental and simulated examples. Finally, several recent developments enabled by MAS are described and some potential future directions are suggested.
History
Source
Annual Reports on NMR SpectroscopyVolume
86Pagination
211 - 236Publisher DOI
ISSN
0066-4103ISBN-13
9780128021231Publication classification
C Journal article; C1 Refereed article in a scholarly journalCopyright notice
2015, ElsevierUsage metrics
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