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Investigation into the application of chiral organotin hydrides as enantioselective free radical reducing agents
thesisposted on 1998-01-01, 00:00 authored by David James. Henry
Investigates the viability of selectively preparing molecules demonstrating the property of left or right "handedness" via free radical reactions. Experimental investigations suggested that a subtle interaction exists between the substituents of an organotin hydride and a target carbon radical during hydrogen atom transfer reactions.