The main focus of our project is to find a novel method to construct graphene hybrid systems and functionalised AuNPs with graphene which opens a new pathway for the potential and highly sensing applications in the area of graphene hybrid nanoarchitecture such as actuators and touch sensors. Adsorption of different CH3 and COOH alkanethiols on the surface of modified Au electrode with different CRGO's sheets to increase the efficient electron pathways for the development of new class graphene electrodes.