α,ω-Bis(trichlorostannyl)alkanes: unravelling the hydrolysis pathway to organotin-oxo oligomers Zobel, Bernhard, Duthie, Andrew, Dakternieks, Dainis and Tiekink, Edward R.T. 2001, α,ω-Bis(trichlorostannyl)alkanes: unravelling the hydrolysis pathway to organotin-oxo oligomers, Organometallics, vol. 20, no. 13, pp. 2820-2826, doi: 10.1021/om010202j. Attached Files Name Description MIMEType Size Downloads Title α,ω-Bis(trichlorostannyl)alkanes: unravelling the hydrolysis pathway to organotin-oxo oligomers Author(s) Zobel, Bernhard Duthie, Andrew Dakternieks, Dainis Tiekink, Edward R.T. Journal name Organometallics Volume number 20 Issue number 13 Start page 2820 End page 2826 Publisher American Chemical Society Place of publication San Diego, Calif Publication date 2001 ISSN 0276-7333 1520-6041 Summary New α,ω-bis(trichlorostannyl)alkanes, Cl3Sn(CH2)nSnCl3 [n = 3-5, 8], have been synthesized via tin-phenyl bond cleavage reactions on α,ω-bis(triphenylstannyl)alkanes, Ph3Sn(CH2)nSnPh3 [n = 3-5, 8], using either SnCl4 or concentrated hydrochloric acid. Some key missing links, (H2O)Cl3Sn(CH2)3SnCl3(H2O) (1a) and (H2O)2Cl3Sn(CH2)3SnCl3(H2O)2 (6), in the hydrolysis pathway of organotin trichlorides were identified. Crystal structures of the nonassociated di-tin compounds (H2O)Cl3Sn(CH2)3SnCl3(H2O) (1a) and (H2O)2Cl3Sn(CH2)3SnCl3(H2O)2 (6, isolated as the 18-crown-6 cocrystal acetonitrile solvate) as well as the polymeric hydrolysis product [H2O(OH)Cl2Sn(CH2)3SnCl2(OH)H2O·2H2O]n (7·2H2O) are reported. Language eng DOI 10.1021/om010202j Field of Research 030204 Main Group Metal Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal Copyright notice ©2001, American Chemical Society Persistent URL http://hdl.handle.net/10536/DRO/DU:30001405 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Biological and Chemical Sciences Related Links Link Description Connect to published version Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 24 Oct 2008, 10:27:59 EST Mon, 01 Jun 2009, 11:26:03 EST Fri, 06 May 2011, 08:47:34 EST Mon, 13 Jan 2014, 14:14:54 EST Fri, 13 Jun 2014, 21:06:47 EST Fri, 17 Oct 2014, 08:06:47 EST Filtered Full Citation counts:   Cited 22 times in TR Web of Science Cited 23 times in Scopus Search Google Scholar Access Statistics: 710 Abstract Views, 3 File Downloads  -  Detailed Statistics Created: Mon, 07 Jul 2008, 07:56:00 EST