α,ω-Bis(trichlorostannyl)alkanes as Bis(monodentate) lewis acids toward halide ions Zobel, Bernhard, Duthie, Andrew, Dakternieks, Dainis and Tiekink, Edward R.T. 2001, α,ω-Bis(trichlorostannyl)alkanes as Bis(monodentate) lewis acids toward halide ions, Organometallics, vol. 20, no. 15, pp. 3347-3350, doi: 10.1021/om010246s. Attached Files Name Description MIMEType Size Downloads Title α,ω-Bis(trichlorostannyl)alkanes as Bis(monodentate) lewis acids toward halide ions Author(s) Zobel, Bernhard Duthie, Andrew Dakternieks, Dainis Tiekink, Edward R.T. Journal name Organometallics Volume number 20 Issue number 15 Start page 3347 End page 3350 Publisher American Chemical Society Place of publication San Diego, Calif Publication date 2001 ISSN 0276-7333 1520-6041 Summary The reactions between X3Sn(CH2)nSnX3 (X = Cl, Br; n = 1, 3, 4, 8) and halide in solution are described. 119Sn NMR spectroscopy (CD2Cl2) indicates formation of five-coordinate dinuclear 1:2 adducts, [X4Sn(CH2)nSnX4]2-, with chloride and bromide. A trigonal-bipyramidal geometry has been confirmed in the solid state for the compound having X = Cl and n = 4. In contrast, fluoride reacts with X3Sn(CH2)nSnX3 to give six-coordinate tin species, [F5Sn(CH2)nSnF5].4- There was no evidence indicating that the tin atoms could act as a bidentate acid. Notes Web Release Date: June 23, 2001 Language eng DOI 10.1021/om010246s Field of Research 030204 Main Group Metal Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal Copyright notice ©2001, American Chemical Society Persistent URL http://hdl.handle.net/10536/DRO/DU:30001406 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Biological and Chemical Sciences Related Links Link Description Connect to published version Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 24 Oct 2008, 10:49:53 EST Mon, 01 Jun 2009, 11:28:29 EST Mon, 13 Jan 2014, 14:13:18 EST Fri, 13 Jun 2014, 21:06:54 EST Fri, 17 Oct 2014, 08:06:52 EST Filtered Full Citation counts:   Cited 12 times in TR Web of Science Cited 13 times in Scopus Search Google Scholar Access Statistics: 697 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Mon, 07 Jul 2008, 07:56:02 EST