Extending distannoxane double ladders using rigid spacers: a double ladder with eight chiral tin atoms-and a twist! Dakternieks, Dainis, Duthie, Andrew, Zobel, Bernhard, Jurkschat, Klaus, Schurmann, Markus and Tiekink, Edward R. T. 2002, Extending distannoxane double ladders using rigid spacers: a double ladder with eight chiral tin atoms-and a twist!, Organometallics, vol. 21, no. 4, pp. 647-652, doi: 10.1021/om0105627. Attached Files Name Description MIMEType Size Downloads Title Extending distannoxane double ladders using rigid spacers: a double ladder with eight chiral tin atoms-and a twist! Author(s) Dakternieks, Dainis Duthie, Andrew Zobel, Bernhard Jurkschat, Klaus Schurmann, Markus Tiekink, Edward R. T. Journal name Organometallics Volume number 21 Issue number 4 Start page 647 End page 652 Publisher American Chemical Society Place of publication San Diego, Calif Publication date 2002 ISSN 0276-7333 1520-6041 Summary The new bulky silicon-containing ditin precursor p-(RCl2SnCH2SiMe2)2C6H4 (R = CH2SiMe3 (4)) has been synthesized and further reacted to form a unique double ladder {[p-(R(Cl)SnCH2SiMe2)2C6H4]O}4 (6). The two layers within 6 are twisted with respect to one another, resulting in a helical motif and a total absence of molecular symmetry so that there are eight chiral tin atoms within the system. The structure is compared to the double ladder {[m-(R(Cl)SnCH2CH2)2C6H4]O}4 (11), which was prepared from the less sterically demanding ditin precursor m-(RCl2SnCH2CH2)2C6H4 (10). The two layers within 11 are parallel, and the molecule contains only two kinds of tin atom. Notes Web Release Date: January 24, 2002 Language eng DOI 10.1021/om0105627 Field of Research 039904 Organometallic Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal Copyright notice ©2002, American Chemical Society Persistent URL http://hdl.handle.net/10536/DRO/DU:30001561 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Biological and Chemical Sciences Related Links Link Description Connect to published version Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Wed, 22 Oct 2008, 10:23:24 EST Mon, 01 Jun 2009, 14:18:55 EST Mon, 13 Jan 2014, 14:15:59 EST Mon, 13 Jan 2014, 14:17:08 EST Fri, 13 Jun 2014, 21:17:58 EST Fri, 17 Oct 2014, 08:08:06 EST Filtered Full Citation counts:   Cited 43 times in TR Web of Science Cited 46 times in Scopus Search Google Scholar Access Statistics: 626 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Mon, 07 Jul 2008, 08:00:22 EST