Secondary bonding in para-substituted diphenyltellurium dichlorides (p-XC6H4)2TeCl2 (X = H, Me, MeO) probed by 125Te MAS NMR spectroscopy. Crystal and molecular structure of (p-MeC6H4)2TeCl2 Beckmann, Jens, Dakternieks, Dainis, Duthie, Andrew and Smith, Naomi A. 2003, Secondary bonding in para-substituted diphenyltellurium dichlorides (p-XC6H4)2TeCl2 (X = H, Me, MeO) probed by 125Te MAS NMR spectroscopy. Crystal and molecular structure of (p-MeC6H4)2TeCl2, Journal of organometallic chemistry, vol. 669, no. 1-2, pp. 149-153, doi: 10.1016/S0022-328X(03)00005-6. Attached Files Name Description MIMEType Size Downloads Title Secondary bonding in para-substituted diphenyltellurium dichlorides (p-XC6H4)2TeCl2 (X = H, Me, MeO) probed by 125Te MAS NMR spectroscopy. Crystal and molecular structure of (p-MeC6H4)2TeCl2 Formatted title Secondary bonding in para-substituted diphenyltellurium dichlorides (p-XC6H4)2TeCl2 (X = H, Me, MeO) probed by 125Te MAS NMR spectroscopy. Crystal and molecular structure of (p-MeC6H4)2TeCl2 Author(s) Beckmann, Jens Dakternieks, Dainis Duthie, Andrew Smith, Naomi A. Journal name Journal of organometallic chemistry Volume number 669 Issue number 1-2 Start page 149 End page 153 Publisher Elsevier Science B.V. Place of publication New York, N.Y. Publication date 2003-03-03 ISSN 0022-328X 1872-8561 Keyword(s) secondary bonding tellurium 125Te MAS NMR spectroscopy x-ray crystallography Summary The solid-state structures of the previously known para-substituted diphenyltellurium dichlorides, (p-XC6H4)2TeCl2 (X=H (1), Me (2), MeO (3)) were investigated by 125Te MAS NMR spectroscopy and in case of 2 by single crystal X-ray diffraction. The 125Te-NMR shielding anisotropy (SA) was studied by tensor analyses based on relative intensities of the observed spinning sidebands. Solid-state NMR parameters, namely the isotropic chemical shift (δiso), anisotropy (ζ) and asymmetry (η), were discussed in relation to the molecular structures established by X-ray crystallography. The asymmetry (η) was found to be particularly sensitive to structural differences stemming mostly from the diverse secondary Te...Cl interactions, but no correlation with geometric parameters could be established. Language eng DOI 10.1016/S0022-328X(03)00005-6 Field of Research 039904 Organometallic Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal Copyright notice ©2003, Elsevier Science B.V. Persistent URL http://hdl.handle.net/10536/DRO/DU:30001958 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Biological and Chemical Sciences Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Thu, 23 Oct 2008, 08:47:27 EST Tue, 02 Jun 2009, 11:13:21 EST Mon, 13 Jan 2014, 14:31:08 EST Fri, 13 Jun 2014, 21:42:55 EST Fri, 17 Oct 2014, 08:10:22 EST Filtered Full Citation counts:   Cited 19 times in TR Web of Science Cited 21 times in Scopus Search Google Scholar Access Statistics: 592 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Mon, 07 Jul 2008, 08:11:22 EST