Synthesis, molecular structure, and isomerisation in solution of (Me3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony Beckmann, Jens, Dakternieks, Dainis, Duthie, Andrew and Foitzik, Richard C. 2003, Synthesis, molecular structure, and isomerisation in solution of (Me3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony, Zeitschrift für anorganische und allgemeine chemie, vol. 629, pp. 1508-1510, doi: 10.1002/zaac.200300102. Attached Files Name Description MIMEType Size Downloads Title Synthesis, molecular structure, and isomerisation in solution of (Me3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony Formatted title Synthesis, molecular structure, and isomerisation in solution of (Me3SbS)2Me2SnCl2. Concomitant hypercoordination of tin and antimony Author(s) Beckmann, Jens Dakternieks, Dainis Duthie, Andrew Foitzik, Richard C. Journal name Zeitschrift für anorganische und allgemeine chemie Volume number 629 Start page 1508 End page 1510 Publisher Wiley Interscience Place of publication Malden, MA. Publication date 2003 ISSN 0044-2313 1521-3749 Keyword(s) tin antimony hypercoordination crystal structures NMR spectroscopy Summary The reaction of Me3SbCl2 and (Me2SnS)3 afforded the complex (Me3SbS)2Me2SnCl2 in high yields, whose molecular structure features both hypercoordinated tin and antimony atoms. In solution, (Me3SbS)2Me2SnCl2 undergoes a reversible dissociation and ligand interchange reaction to give Me3SbS, Me3SbCl2 and (Me2SnS)3. Notes Published Online: 11 Aug 2003 Language eng DOI 10.1002/zaac.200300102 Field of Research 039904 Organometallic Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal Copyright notice ©2003, WILEY-VCH Verlag Persistent URL http://hdl.handle.net/10536/DRO/DU:30002060 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Biological and Chemical Sciences Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 24 Oct 2008, 11:57:00 EST Tue, 02 Jun 2009, 14:01:50 EST Tue, 02 Jun 2009, 14:03:37 EST Mon, 13 Jan 2014, 14:38:36 EST Fri, 13 Jun 2014, 21:51:01 EST Fri, 17 Oct 2014, 08:11:19 EST Filtered Full Citation counts:   Cited 5 times in TR Web of Science Cited 5 times in Scopus Search Google Scholar Access Statistics: 600 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Mon, 07 Jul 2008, 08:14:12 EST