Near-ultraviolet chemiluminescence from the reaction of ammonia with hypobromite in aqueous solution Francis, Paul S., Adcock, Jacqui L. and Barnett, Neil W. 2006, Near-ultraviolet chemiluminescence from the reaction of ammonia with hypobromite in aqueous solution, Spectrochimica acta. Part A, molecular and biomolecular spectroscopy, vol. 65, no. 3-4, pp. 708-710, doi: 10.1016/j.saa.2005.12.033. Attached Files Name Description MIMEType Size Downloads Title Near-ultraviolet chemiluminescence from the reaction of ammonia with hypobromite in aqueous solution Author(s) Francis, Paul S. orcid.org/0000-0003-4165-6922 Adcock, Jacqui L. orcid.org/0000-0002-4446-518X Barnett, Neil W. Journal name Spectrochimica acta. Part A, molecular and biomolecular spectroscopy Volume number 65 Issue number 3-4 Start page 708 End page 710 Publisher Elsevier BV Place of publication Amsterdam, Netherlands Publication date 2006-11 ISSN 1386-1425 0584-8539 Keyword(s) near-ultraviolet chemiluminescence ammonia hypohalites molecular nitrogen Summary The chemiluminescence arising from the oxidation of ammonium chloride by sodium hypobromite in aqueous alkaline solution includes a series of peaks in the near-ultraviolet, which is not commonly observed in liquid-phase chemiluminescence. The dominant peak in that region has an intensity maximum at 292 nm and smaller peaks are observed at 313, 334 and 356 nm. The emitted photons are of similar energy to the Vergard–Kaplan transition of molecular nitrogen, a major product of this reaction. However, the spectral distribution is different to that of previously reported gas-phase chemiluminescence attributed to the Vergard–Kaplan transition. Notes Available online 21 February Language eng DOI 10.1016/j.saa.2005.12.033 Field of Research 030606 Structural Chemistry and Spectroscopy Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal Copyright notice ©2005 Elsevier B.V. Persistent URL http://hdl.handle.net/10536/DRO/DU:30003652 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Life and Environmental Sciences Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Mon, 03 Nov 2008, 10:41:18 EST Thu, 04 Jun 2009, 11:07:40 EST Fri, 26 Mar 2010, 14:30:07 EST Tue, 03 Sep 2013, 11:38:42 EST Tue, 08 Apr 2014, 10:46:53 EST Fri, 22 Aug 2014, 16:08:08 EST Wed, 27 Aug 2014, 21:22:45 EST Fri, 17 Oct 2014, 08:25:42 EST Filtered Full Citation counts:   Cited 14 times in TR Web of Science Cited 15 times in Scopus Search Google Scholar Access Statistics: 1274 Abstract Views, 4 File Downloads  -  Detailed Statistics Created: Mon, 07 Jul 2008, 08:59:16 EST