Steric and electronic factors influencing recognition by a simple, charge neutral norbornene based anion receptor
Lowe, Adam, Dyson, Gail and Pfeffer, Frederick 2007, Steric and electronic factors influencing recognition by a simple, charge neutral norbornene based anion receptor, Organic and biomolecular chemistry, vol. 5, pp. 1343-1346, doi: 10.1039/b703626b.
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Steric and electronic factors influencing recognition by a simple, charge neutral norbornene based anion receptor
Based on 1H NMR studies, subtle electronic factors rather than pre-organisation dictate the binding stoichiometry of the new, norbornene based, anion hosts 1 and 2 with acetate, however, the binding of dihydrogenphosphate appears to be based solely on steric constraints.
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First published as an Advance Article on the web 22nd March 2007
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