Hydrolysis of bis((trimethylsilyl)methyl)tin dihalides. Crystallographic and spectroscopic study of the hydrolysis pathway Beckmann, Jens, Henn, Markus, Jurkschat, Klaus, Schurmann, Markus, Dakternieks, Dainis and Duthie, Andrew 2002, Hydrolysis of bis((trimethylsilyl)methyl)tin dihalides. Crystallographic and spectroscopic study of the hydrolysis pathway, Organometallics, vol. 21, no. 1, pp. 192-202, doi: 10.1021/om010715q. Attached Files Name Description MIMEType Size Downloads Title Hydrolysis of bis((trimethylsilyl)methyl)tin dihalides. Crystallographic and spectroscopic study of the hydrolysis pathway Author(s) Beckmann, Jens Henn, Markus Jurkschat, Klaus Schurmann, Markus Dakternieks, Dainis Duthie, Andrew Journal name Organometallics Volume number 21 Issue number 1 Start page 192 End page 202 Publisher ACS Publications Place of publication San Diego, Calif Publication date 2002 ISSN 0276-7333 1520-6041 Summary The synthesis and characterization by multinuclear NMR spectroscopy of the diorganotin dihalides (Me3SiCH2)2SnX2 (1, X = Cl; 2, X = Br), the diorganotin dichloride water adduct (Me3SiCH2)2SnCl2·H2O (1a), the dimeric tetraorganodistannoxanes [(Me3SiCH2)2(X)SnOSn(Y)(CH2SiMe3)2]2 (3, X = Y = Cl; 4, X = Br, Y = OH; 5, X = Br, Y = F; 6, X = Y = OH; 8, X = Cl, Y = OH), and the molecular diorganotin oxide cyclo-[(Me3SiCH2)2SnO]3 (7) are reported. The structures in the solid state of compounds 1a, 3, 6, and 7 were determined by single-crystal X-ray analysis. In toluene solution, the hydroxy-substituted tetraorganodistannoxane 6 is in equilibrium with the diorganotin oxide 7 and water. The eight-membered diorganotin oxide cyclo-[(Me3SiCH2)2SnO]4 (7a) is proposed to be involved in this equilibrium. On the basis of the results of this and previous works, a general hydrolysis pathway is developed for diorganotin dichlorides containing reasonably bulky substituents. Notes Web Release Date: December 11, 2001 Language eng DOI 10.1021/om010715q Field of Research 039904 Organometallic Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal ERA Research output type C Journal article Copyright notice ©2002, American Chemical Society Persistent URL http://hdl.handle.net/10536/DRO/DU:30008509 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Biological and Chemical Sciences Related Links Link Description Connect to published version Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Thu, 23 Oct 2008, 07:25:28 EST Tue, 09 Jun 2009, 14:01:33 EST Tue, 14 Jan 2014, 09:00:59 EST Mon, 16 Jun 2014, 09:19:23 EST Fri, 17 Oct 2014, 09:03:43 EST Filtered Full Citation counts:   Cited 57 times in TR Web of Science Cited 0 times in Scopus Search Google Scholar Access Statistics: 624 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Mon, 13 Oct 2008, 15:34:06 EST