The reactivity of bis(para-methoxyphenyl)telluroxide towards triflic acid and diphenylphosphinic acid. Theoretical considerations of the protonation and hydration process of diorganotelluroxanes Beckmann, Jens, Dakternieks, Dainis, Duthie, Andrew, Lewcenko, Naomi A., Mitchell, Cassandra and Schurmann, Markus 2005, The reactivity of bis(para-methoxyphenyl)telluroxide towards triflic acid and diphenylphosphinic acid. Theoretical considerations of the protonation and hydration process of diorganotelluroxanes, Zeitschrift für anorganische und allgemeine chemie, vol. 631, no. 10, pp. 1856-1862, doi: 10.1002/zaac.200500168. Attached Files Name Description MIMEType Size Downloads Title The reactivity of bis(para-methoxyphenyl)telluroxide towards triflic acid and diphenylphosphinic acid. Theoretical considerations of the protonation and hydration process of diorganotelluroxanes Formatted title Reactivity of bis(para-methoxyphenyl)telluroxide towards triflic acid and diphenylphosphinic acid. Theoretical considerations of the protonation and hydration process of diorganotelluroxanes Author(s) Beckmann, Jens Dakternieks, Dainis Duthie, Andrew Lewcenko, Naomi A. Mitchell, Cassandra Schurmann, Markus Journal name Zeitschrift für anorganische und allgemeine chemie Volume number 631 Issue number 10 Start page 1856 End page 1862 Publisher Wiley Interscience Place of publication Malden, MA. Publication date 2005 ISSN 0044-2313 1521-3749 Keyword(s) tellurium organometallic hypervalent compounds density functional calculations Summary The reaction of (p-MeOC6H4)2TeO with two equivalents of HO3SCF3 and HO2PPh2 provided the tetraorganoditelluroxanes (F3CSO3)(p-MeOC6H4)2TeOTe(p-MeOC6H4)2(O3SCF3) (1) and (Ph2PO2)(p-MeOC6H4)2TeOTe(p-MeOC6H4)2(O2PPh2)·2 Ph2PO2H (2) in good yields. Compounds 1 and 2 were characterized by solution and solid-state 31P and 125Te NMR spectroscopy, IR spectroscopy, electrospray mass spectrometry, conductivity measurements and single crystal X-ray diffraction. In solution, compound 1 undergoes an electrolytic dissociation and reversibly reacts with traces of water to give the mononuclear cation [(p-MeOC6H4)2TeOH]+ and triflate anions. Theoretical aspects of the protonation and hydration of model telluroxanes R2TeO (R = H, Me, Ph) were investigated by preliminary DFT calculations and compared to the corresponding selenoxanes R2SeO. The tellurium dihydroxides R2Te(OH)2 seem to be more stable than the hydrogen-bonded complexes R2TeO·H2O. Notes Published Online: 26 Jul 2005 Language eng DOI 10.1002/zaac.200500168 Field of Research 039904 Organometallic Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal ERA Research output type C Journal article Copyright notice ©2005, WILEY-VCH Verlag Persistent URL http://hdl.handle.net/10536/DRO/DU:30008883 Document type: Journal Article Collection: School of Biological and Chemical Sciences Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 24 Oct 2008, 11:50:36 EST Wed, 10 Jun 2009, 11:55:54 EST Tue, 14 Jan 2014, 09:35:35 EST Mon, 16 Jun 2014, 09:45:34 EST Fri, 17 Oct 2014, 09:05:57 EST Filtered Full Citation counts:   Cited 24 times in TR Web of Science Cited 24 times in Scopus Search Google Scholar Access Statistics: 638 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Mon, 13 Oct 2008, 15:44:50 EST