Reactive ball milling to produce nanocrystalline ZnO
Glushenkov, A. M., Zhang, H.Z. and Chen, Y. 2008, Reactive ball milling to produce nanocrystalline ZnO, Materials letters, vol. 62, no. 24, pp. 4047-4049, doi: 10.1016/j.matlet.2008.06.002.
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Reactive ball milling to produce nanocrystalline ZnO
Ball milling of zinc powders in oxygen atmosphere leads to nanocrystalline ZnO. The average grain size has a value of 9 nm. The zinc oxidation proceeds gradually. It is compared with the combustion oxidation reactions of metals (Zr, Ti, Fe and Sn) reported previously. We propose a new parameter ΔH/Cp(metal) instead of simplified adiabatic temperature to judge if the mechanochemical oxidation of a particular metal happens via gradual or combustion reaction.
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