Simple naphthalimide based anion sensors: deprotonation induced colour changes and CO2 fixation
Gunnlaugsson, Thorfinnur, Kruger, Paul E., Jensen, Paul, Pfeffer, Frederick M. and Hussey, Gillian M. 2003, Simple naphthalimide based anion sensors: deprotonation induced colour changes and CO2 fixation, Tetrahedron letters, vol. 44, no. 49, pp. 8909-8913, doi: 10.1016/j.tetlet.2003.09.148.
Attached Files
Name
Description
MIMEType
Size
Downloads
Title
Simple naphthalimide based anion sensors: deprotonation induced colour changes and CO2 fixation
Formatted title
Simple naphthalimide based anion sensors: deprotonation induced colour changes and CO2 fixation
The 4-amino-1,8-naphthalimide based chemosensors 2, 4 and 6 show striking green-to-purple colour changes due to the deprotonation of the 4-amino moiety on interaction with strongly basic anions such as F−: these colour changes reverse gradually with time due to the fixation of atmospheric CO2 (as HCO3−) yielding 1:1 adducts as demonstrated by X-ray crystallography.
Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.