Ionic conductivity in poly(diethylene glycol-carbonate)/sodium triflate complexes

Forsyth, M., Tipton, A. L., Shriver, D. F., Ratner, M. A. and MacFarlane, D. R. 1997, Ionic conductivity in poly(diethylene glycol-carbonate)/sodium triflate complexes, Solid state ionics, vol. 99, no. 3-4, pp. 257-261, doi: 10.1016/S0167-2738(97)00115-X.

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Title Ionic conductivity in poly(diethylene glycol-carbonate)/sodium triflate complexes
Author(s) Forsyth, M.ORCID iD for Forsyth, M.
Tipton, A. L.
Shriver, D. F.
Ratner, M. A.
MacFarlane, D. R.
Journal name Solid state ionics
Volume number 99
Issue number 3-4
Start page 257
End page 261
Publisher Elsevier
Place of publication Amsterdam, The Netherlands
Publication date 1997-08-02
ISSN 0167-2738
Keyword(s) Ion conductivity
polymer electrolyte
Summary New polymer electrolytes were synthesized and characterized based on a new polymer host. The motivation was to produce a host polymer with a high dielectric constant which should reduce ion clustering with an attendant increased conductivity. The new polymer host, poly(diethylene glycol carbonate) and its sodium triflate complexes were characterized by thermal analysis and AC impedance measurements. The polycarbonate backbone appears less flexible than the polyether hosts as evidenced by the higher glass transition temperatures. The conductivity for the sodium triflate complexes was measured as ~ 10−5 S cm−1 at 55 °C and the dielectric constant of the host polymer was found to be 3.6 at 3 GHz. The low conductivity is attributed to rigidity of the polycarbonate.
Language eng
DOI 10.1016/S0167-2738(97)00115-X
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©1997, Elsevier Science B.V.
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