Fast ion conduction in molecular plastic crystals Long, S., MacFarlane, D. R. and Forsyth, M. 2003, Fast ion conduction in molecular plastic crystals, Solid state ionics, vol. 161, no. 1-2, pp. 105-112, doi: 10.1016/S0167-2738(03)00208-X. Attached Files Name Description MIMEType Size Downloads Title Fast ion conduction in molecular plastic crystals Author(s) Long, S. MacFarlane, D. R. Forsyth, M. orcid.org/0000-0002-4273-8105 Journal name Solid state ionics Volume number 161 Issue number 1-2 Start page 105 End page 112 Publisher Elsevier Place of publication Amsterdam, The Netherlands Publication date 2003-07 ISSN 0167-2738 1872-7689 Keyword(s) succinonitrile ionic conductivity ion transport lithium acid solid electrolytes Summary Doping of lithium salts and acids into the plastic crystal phase of succinonitrile has shown for the first time of the possibility of creating solid state electrolytes based on plastic crystalline solvents where the matrix itself is neutral and hence not intrinsically conductive. These materials illustrate the concept of a solid state electrolyte solvent. Room temperature conductivities up to 3.4×10−4 S cm−1 were obtained with 5 wt.% lithium bis(trifluoromethanesulfonylamide) in succinonitrile. Pulsed field gradient NMR measurements indicate that both cation and anion are mobile in this lattice. Proton conductivity was also observed when methane sulfonic acid or glacial acetic acid was used as dopants, however, the conductivity in these systems is limited by the poor dissociating ability of these acids. Language eng DOI 10.1016/S0167-2738(03)00208-X Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2003, Elsevier B.V. Persistent URL http://hdl.handle.net/10536/DRO/DU:30030182 Document type: Journal Article Collections: Institute for Technology Research and Innovation GTP Research Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:09:50 EST Thu, 16 Sep 2010, 15:13:13 EST Thu, 16 Sep 2010, 15:14:52 EST Mon, 16 Jun 2014, 16:26:33 EST Filtered Full Citation counts:   Cited 122 times in TR Web of Science Cited 126 times in Scopus Search Google Scholar Access Statistics: 975 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:09:50 EST

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