High conductivity molten salts based on the imide ion

McFarlane, D. R., Sun, J., Golding, J., Meakin, P. and Forsyth, M. 2000, High conductivity molten salts based on the imide ion, Electrochimica acta, vol. 45, no. 8-9, pp. 1271-1278, doi: 10.1016/S0013-4686(99)00331-X.

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Title High conductivity molten salts based on the imide ion
Author(s) McFarlane, D. R.
Sun, J.
Golding, J.
Meakin, P.
Forsyth, M.ORCID iD for Forsyth, M. orcid.org/0000-0002-4273-8105
Journal name Electrochimica acta
Volume number 45
Issue number 8-9
Start page 1271
End page 1278
Publisher Elsevier Science Pub. Co.
Place of publication New York, N.Y.
Publication date 2000-01-03
ISSN 0013-4686
Keyword(s) molten salts
imide anion
Bis(trifluoromethanesulfonyl) amide ion
Summary The bis(trifluoromethanesulfonyl)imide ion has recently been used in its lithium salt as a useful ion in solid polymer electrolytes because of the reduced degree of ion interaction its diffuse charge generates. In this work we have synthesised a number of novel salts based on the ammonium and pyrrolidinium cations of this anion. The salts all show reduced melting points compared with analogous halide salts. In some cases they are molten at room temperature. This latter group of salts have been characterized with respect to their properties as ionic liquids; the highest room temperature conductivity 2 mS cm−1 being exhibited by methyl butyl pyrrolidinium imide. Many of the salts are glass forming, exhibiting glass transition temperatures in the region of −90°C.
Language eng
DOI 10.1016/S0013-4686(99)00331-X
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2000, Elsevier Science Ltd.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030215

Document type: Journal Article
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