Synthesis and physical property characterisation of phosphonium ionic liquids based on P(O)2(OR)2− and P(O)2(R)2− anions with potential application for corrosion mitigation of magnesium alloys Sun, Jiazeng, Howlett, Patrick C., MacFarlane, Douglas R., Lin, Ji and Forsyth, Maria 2008, Synthesis and physical property characterisation of phosphonium ionic liquids based on P(O)2(OR)2− and P(O)2(R)2− anions with potential application for corrosion mitigation of magnesium alloys, Electrochimica acta, vol. 54, no. 2, pp. 254-260, doi: 10.1016/j.electacta.2008.08.020. Attached Files Name Description MIMEType Size Downloads Title Synthesis and physical property characterisation of phosphonium ionic liquids based on P(O)2(OR)2− and P(O)2(R)2− anions with potential application for corrosion mitigation of magnesium alloys Formatted title Synthesis and physical property characterisation of phosphonium ionic liquids based on P(O)2(OR)2− and P(O)2(R)2− anions with potential application for corrosion mitigation of magnesium alloys Author(s) Sun, Jiazeng Howlett, Patrick C. orcid.org/0000-0002-2151-2932 MacFarlane, Douglas R. Lin, Ji Forsyth, Maria orcid.org/0000-0002-4273-8105 Journal name Electrochimica acta Volume number 54 Issue number 2 Start page 254 End page 260 Total pages 7 Publisher Elsevier Place of publication New York, N.Y. Publication date 2008-12-30 ISSN 0013-4686 1873-3859 Keyword(s) ionic liquids conductivity transport properties corrosion Summary Phosphonium cation based ionic liquids (ILs) have become of interest due to their unique chemical and electrochemical stability as well as their promising tribological properties. At the same time, interest has also grown in the use of phosphate and phosphinate based ionic liquids for corrosion protection of reactive metals. In this work we describe the synthesis and characterization of six novel ionic liquids based on the tetraalkylphosponium cation coupled with organophosphate and organophosphinate anions and their sulfur analogues. The conductivity and viscosity of these ILs has been measured and discussed in terms of the nature of the interactions, effect of anion basicity and the extent of ionic character. The reaction of the IL with a ZE41 magnesium aerospace alloy surface is also demonstrated. Language eng DOI 10.1016/j.electacta.2008.08.020 Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2008, Elsevier Persistent URL http://hdl.handle.net/10536/DRO/DU:30030263 Document type: Journal Article Collections: Institute for Technology Research and Innovation GTP Research Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:11:18 EST Tue, 21 Sep 2010, 10:48:32 EST Tue, 21 Sep 2010, 10:50:01 EST Thu, 09 Jan 2014, 10:42:39 EST Thu, 11 Dec 2014, 16:44:48 EST Filtered Full Citation counts:   Cited 72 times in TR Web of Science Cited 86 times in Scopus Search Google Scholar Access Statistics: 1153 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:11:18 EST