A new Lewis-base ionic liquid comprising a mono-charged diamine structure : a highly stable electrolyte for lithium electrochemistry Yoshizawa-Fujita, Masahiro, MacFarlane, Douglas R., Howlett, Patrick C. and Forsyth, Maria 2006, A new Lewis-base ionic liquid comprising a mono-charged diamine structure : a highly stable electrolyte for lithium electrochemistry, Electrochemistry communications, vol. 8, no. 3, pp. 445-449, doi: 10.1016/j.elecom.2006.01.008. Attached Files Name Description MIMEType Size Downloads Title A new Lewis-base ionic liquid comprising a mono-charged diamine structure : a highly stable electrolyte for lithium electrochemistry Author(s) Yoshizawa-Fujita, Masahiro MacFarlane, Douglas R. Howlett, Patrick C. orcid.org/0000-0002-2151-2932 Forsyth, Maria orcid.org/0000-0002-4273-8105 Journal name Electrochemistry communications Volume number 8 Issue number 3 Start page 445 End page 449 Publisher Elsevier Place of publication Amsterdam, The Netherlands Publication date 2006-03 ISSN 1388-2481 1873-1902 Keyword(s) ionic liquid lewis base lithium electrochemistry ionic conductivity Summary A new Lewis-base ionic liquid (IL) based on mono-charged 1,4-diazabicyclo[2.2.2]octane (dabco) was synthesized and its thermal and electrochemical behaviour was characterized. The dabco-based IL with bis(trifluoromethanesulfonyl)amide (TFSA) anion melts at 76 °C when the N-substituted alkyl chain length is 2. The dabco-based IL showed a wide electrochemical window of over 4 V ranging from −3.5 to +1.5 V vs. Fc/Fc+ and was able to deposit and strip lithium from a nickel substrate at reasonable efficiency. Language eng DOI 10.1016/j.elecom.2006.01.008 Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2006, Elsevier B.V. Persistent URL http://hdl.handle.net/10536/DRO/DU:30030298 Document type: Journal Article Collections: Institute for Technology Research and Innovation GTP Research Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:11:54 EST Wed, 13 Oct 2010, 14:46:38 EST Wed, 13 Oct 2010, 14:48:46 EST Wed, 13 Oct 2010, 14:55:12 EST Mon, 09 May 2011, 17:05:28 EST Thu, 09 Jan 2014, 10:43:27 EST Mon, 16 Jun 2014, 16:30:20 EST Filtered Full Citation counts:   Cited 48 times in TR Web of Science Cited 54 times in Scopus Search Google Scholar Access Statistics: 1194 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:11:54 EST