Autocatalytic nature of permanganate oxidations exploited for highly sensitive chemiluminescence detection Slezak, Teo, Terry, Jessica M., Francis, Paul S., Hindson, Christopher M., Olson, Don C., Wolcott, Duane K. and Barnett, Neil W. 2010, Autocatalytic nature of permanganate oxidations exploited for highly sensitive chemiluminescence detection, Analytical chemistry, vol. 82, no. 6, pp. 2580-2584, doi: 10.1021/ac9028399. Attached Files Name Description MIMEType Size Downloads Title Autocatalytic nature of permanganate oxidations exploited for highly sensitive chemiluminescence detection Author(s) Slezak, Teo Terry, Jessica M. Francis, Paul S. orcid.org/0000-0003-4165-6922 Hindson, Christopher M. Olson, Don C. Wolcott, Duane K. Barnett, Neil W. Journal name Analytical chemistry Volume number 82 Issue number 6 Start page 2580 End page 2584 Total pages 5 Publisher American Chemical Society Place of publication Washington, D.C. Publication date 2010-03-15 ISSN 0003-2700 1520-6882 Summary Manganese(II) salts catalyze the chemiluminescent oxidation of organic compounds with acidic potassium permanganate. The formation of insoluble manganese(IV) species from the reaction between manganese(II) and permanganate can be prevented with sodium polyphosphate, and therefore, relatively high concentrations of the catalyst can be added to the reagent before the lightproducing reaction is initiated. The rapid and intense emissions from these manganese(II) catalyzed chemiluminescence reactions provide highly sensitive detection and greater compatibility with liquid chromatography. Notes Publication Date (Web): February 17, 2010 Language eng DOI 10.1021/ac9028399 Field of Research 030101 Analytical Spectrometry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal HERDC collection year 2010 Copyright notice ©2010, American Chemical Society Persistent URL http://hdl.handle.net/10536/DRO/DU:30031408 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Life and Environmental Sciences Institute for Technology Research and Innovation GTP Research Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Wed, 01 Dec 2010, 10:32:58 EST Wed, 01 Dec 2010, 10:34:07 EST Fri, 03 Dec 2010, 13:16:32 EST Fri, 03 Dec 2010, 13:21:09 EST Fri, 03 Dec 2010, 13:26:56 EST Wed, 08 Jun 2011, 15:09:20 EST Thu, 03 Oct 2013, 10:51:28 EST Mon, 16 Jun 2014, 16:54:59 EST Fri, 22 Aug 2014, 14:55:47 EST Wed, 27 Aug 2014, 22:29:38 EST Fri, 06 Feb 2015, 10:39:38 EST Filtered Full Citation counts:   Cited 24 times in TR Web of Science Cited 23 times in Scopus Search Google Scholar Access Statistics: 951 Abstract Views, 4 File Downloads  -  Detailed Statistics Created: Wed, 01 Dec 2010, 10:32:57 EST by Teresa Treffry