Nitrile functionalized methimazole-based ionic liquids

Siriwardana, Amal I., Torriero, Angel. A. J., Reyna-Gonzälez, Juan M., Burgar, Iko M., Dunlop, Noel F., Bond, Alan M., Deacon, Glen B. and MacFarlane, Douglas R. 2010, Nitrile functionalized methimazole-based ionic liquids, Journal of organic chemistry, vol. 75, no. 24, pp. 8376-8382, doi: 10.1021/jo101449q.

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Title Nitrile functionalized methimazole-based ionic liquids
Author(s) Siriwardana, Amal I.
Torriero, Angel. A. J.ORCID iD for Torriero, Angel. A. J. orcid.org/0000-0001-8616-365X
Reyna-Gonzälez, Juan M.
Burgar, Iko M.
Dunlop, Noel F.
Bond, Alan M.
Deacon, Glen B.
MacFarlane, Douglas R.
Journal name Journal of organic chemistry
Volume number 75
Issue number 24
Start page 8376
End page 8382
Total pages 7
Publisher American Chemical Society
Place of publication San Diego, Calif.
Publication date 2010-11-16
ISSN 0022-3263
1520-6904
Summary The alkylation reaction of 2-mercapto-1-methylimidazole 1b with 2-chloroacetonitrile and 2-chloropropionitrile produced S-alkyl methimazole chlorides 2a and 2b which were subjected to anion metathesis with lithium bis(trifluoromethanesulfonyl)amide, LiNTf2, to afford nitrile functionalized methimazole-based room temperature ionic liquids 3a and 3b in 94% and 89% yields, respectively. Ionic liquids 3a and 3b have reasonably wide electrochemical windows. The efficient extraction of Ag+ from aqueous media into 3a and 3b is also reported.
Language eng
DOI 10.1021/jo101449q
Field of Research 030505 Physical Organic Chemistry
030604 Electrochemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2010, American Chemical Society
Persistent URL http://hdl.handle.net/10536/DRO/DU:30038936

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