Effects of corrosion inhibiting pigment lanthanum 4-hydroxy cinnamate on the filiform corrosion of coated steel
Catubig, Rainier, Seter, Marianne, Neil, Wayne, Forsyth, Maria and Hinton, Bruce 2011, Effects of corrosion inhibiting pigment lanthanum 4-hydroxy cinnamate on the filiform corrosion of coated steel, Journal of the electrochemical society, vol. 158, no. 11, pp. C353-C358.
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Effects of corrosion inhibiting pigment lanthanum 4-hydroxy cinnamate on the filiform corrosion of coated steel
Corrosion protection by lanthanum hydroxy cinnamate (La(4OH-cin)3) in a polyurethane based varnish coating for mild steelhas been investigated. Filiform scribe tests, energy-dispersive X-ray spectroscopy (EDXS) and potentiodynamic polarisation (PP)techniques have been powerful tools to better understand the corrosion process at defects and under the coating. Filiform scribetests showed that La(4OH-cin)3, as a pigment in a coating, inhibited the initiation and propagation of both delamination and filiformcorrosion (FFC) on coated steel. The PP experiments provided an insight into the fundamental mechanism of FFC. The resultssuggest that La(4OH-cin)3 behaves as a mixed inhibitor and stifles the initiation and propagation of FFC. In this paper, the theory ofdelamination leading to FFC and the likely mechanism of inhibition by the La(4OH-cin)3 will be discussed.
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eng
Field of Research
090403 Chemical Engineering Design
Socio Economic Objective
970103 Expanding Knowledge in the Chemical Sciences
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