Synthesis and structure of an intramolecularly coordinated diaryltelluronic acid and its dimethyl ester Beckmann, Jens, Bolsinger, Jens, Duthie, Andrew and Finke, Pamela 2012, Synthesis and structure of an intramolecularly coordinated diaryltelluronic acid and its dimethyl ester, Organometallics, vol. 31, no. 1, pp. 289-293. Attached Files Name Description MIMEType Size Downloads Title Synthesis and structure of an intramolecularly coordinated diaryltelluronic acid and its dimethyl ester Author(s) Beckmann, Jens Bolsinger, Jens Duthie, Andrew Finke, Pamela Journal name Organometallics Volume number 31 Issue number 1 Start page 289 End page 293 Total pages 5 Publisher American Chemical Society Place of publication Washington, D.C. Publication date 2012 ISSN 0276-7333 1520-6041 Keyword(s) derivatives exchange atoms Summary The oxidation of the telluroxane cluster (8Me2NC10H6Te)6O8(OH)2 (4) or the diaryl ditelluride (8-Me2NC10H6Te)(2) (7) using H2O2 provided the diarylditelluronic acid [8-Me2NC10H6Te(O)(OH)2]2(O) (6), which is the second member of this compound class and the first one to contain an intramolecularly coordinated substituent. Attempts at recrystallizing 6 from Methanol provided the partial ester [8-Me2NC10H6Te(O)(OH)(OMe)]2(O) (8). In addition structural motifs of known diaryltelluronic acids were compared using DFT calculations. Language eng Field of Research 039904 Organometallic Chemistry Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1 Refereed article in a scholarly journal Copyright notice ©2012, American Chemical Society Persistent URL http://hdl.handle.net/10536/DRO/DU:30047049 Document type: Journal Article Collections: Faculty of Science, Engineering and Built Environment School of Life and Environmental Sciences   Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Mon, 13 Aug 2012, 13:10:15 EST Mon, 10 Sep 2012, 13:29:35 EST Mon, 10 Sep 2012, 13:31:55 EST Mon, 10 Sep 2012, 13:32:50 EST Sun, 29 Sep 2013, 15:55:20 EST Mon, 30 Sep 2013, 08:47:28 EST Tue, 14 Jan 2014, 09:53:52 EST Fri, 13 Jun 2014, 14:47:28 EST Fri, 17 Oct 2014, 11:41:13 EST Filtered Full Citation counts:   Cited 12 times in TR Web of Science Cited 13 times in Scopus Search Google Scholar Access Statistics: 211 Abstract Views, 2 File Downloads  -  Detailed Statistics Created: Mon, 13 Aug 2012, 13:10:15 EST