Pressure- and heat-induced insertion of CO2 into an auxetic small-pore zeolite

Lee, Yongjae, Liu, Dan, Seoung, Donghoon, Liu, Zhenxian, Kao, Chi-Chang and Vogt, Thomas 2011, Pressure- and heat-induced insertion of CO2 into an auxetic small-pore zeolite, Journal of the American chemical society, vol. 133, no. 6, pp. 1674-1677, doi: 10.1021/ja109765d.

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Title Pressure- and heat-induced insertion of CO2 into an auxetic small-pore zeolite
Author(s) Lee, Yongjae
Liu, DanORCID iD for Liu, Dan
Seoung, Donghoon
Liu, Zhenxian
Kao, Chi-Chang
Vogt, Thomas
Journal name Journal of the American chemical society
Volume number 133
Issue number 6
Start page 1674
End page 1677
Total pages 4
Publisher American Chemical Society
Place of publication Washington, D. C.
Publication date 2011-02-16
ISSN 0002-7863
Keyword(s) pressure release
small-pore zeolites
unit-cell volume
Summary When the small-pore zeolite natrolite is compressed at ca. 1.5 GPa and heated to ca. 110 °C in the presence of CO2, the unit cell volume of natrolite expands by 6.8% and ca. 12 wt % of CO2 is contained in the expanded elliptical channels. This CO2 insertion into natrolite is found to be reversible upon pressure release.
Language eng
DOI 10.1021/ja109765d
Field of Research 020406 Surfaces and Structural Properties of Condensed Matter
040306 Mineralogy and Crystallography
020503 Nonlinear Optics and Spectroscopy
Socio Economic Objective 869802 Management of Greenhouse Gas Emissions from Manufacturing Activities
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2011, American Chemical Society
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