The influence of water and metal ions on the transport properties of Trihexyl(tetradecyl)phosphonium chloride Bayley, Paul M., Novak, Jan, Khoo, Timothy, Britton, Melanie M., Howlett, Patrick C., Macfarlane, Douglas R. and Forsyth, Maria 2012, The influence of water and metal ions on the transport properties of Trihexyl(tetradecyl)phosphonium chloride, Australian journal of chemistry, vol. 65, no. 11, pp. 1542-1547, doi: 10.1071/CH12332. Attached Files Name Description MIMEType Size Downloads Title The influence of water and metal ions on the transport properties of Trihexyl(tetradecyl)phosphonium chloride Author(s) Bayley, Paul M. Novak, Jan Khoo, Timothy Britton, Melanie M. Howlett, Patrick C. orcid.org/0000-0002-2151-2932 Macfarlane, Douglas R. Forsyth, Maria orcid.org/0000-0002-4273-8105 Journal name Australian journal of chemistry Volume number 65 Issue number 11 Start page 1542 End page 1547 Total pages 6 Publisher CSIRO Publishing Place of publication Melbourne, Vic. Publication date 2012 ISSN 0004-9425 1445-0038 Summary A recent study indicated that the water-saturated ionic liquid (IL) trihexyl(tetradecyl)phosphonium chloride ([P6,6,6,14][Cl]) provided a viable electrolyte for a Mg-air battery. However, there is limited literature on the properties of IL-water mixtures as battery electrolytes. The physical properties of [P6,6,6,14][Cl] were studied with the addition of both water and metal salts (MgCl2 and LiCl) using conductivity and self-diffusion coefficient measurements. The conductivity of the samples at low water concentrations is surprisingly enhanced by the addition of the metal salt, contrary to lithium IL electrolytes. It was also found that the conductivity of the IL was increased by an order of magnitude by saturation with water. NMR diffusion measurements were used to probe the behaviour of both the cation and the water in the mixtures. It was found that the addition of metal salts to the water-saturated [P6,6,6,14][Cl] did not affect the transport properties of the water or cation. Language eng DOI 10.1071/CH12332 Field of Research 030304 Physical Chemistry of Materials Socio Economic Objective 970109 Expanding Knowledge in Engineering HERDC Research category C1 Refereed article in a scholarly journal Persistent URL http://hdl.handle.net/10536/DRO/DU:30052681 Document type: Journal Article Collections: Institute for Frontier Materials GTP Research Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Mon, 27 May 2013, 14:10:29 EST Tue, 28 May 2013, 08:43:26 EST Wed, 29 May 2013, 10:39:50 EST Tue, 04 Jun 2013, 14:08:37 EST Tue, 04 Jun 2013, 15:32:29 EST Tue, 04 Jun 2013, 15:34:15 EST Mon, 17 Jun 2013, 18:18:24 EST Fri, 13 Jun 2014, 17:24:29 EST Filtered Full Citation counts:   Cited 10 times in TR Web of Science Cited 10 times in Scopus Search Google Scholar Access Statistics: 860 Abstract Views, 3 File Downloads  -  Detailed Statistics Created: Mon, 27 May 2013, 14:10:13 EST by Nadine Langeder

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